How can you actually measure decay constants?

Question

I'm trying to understand how people actually measure decay constants that are discussed in meson decays. As a concrete example lets consider the pion decay constant. The amplitude for $\pi ^-$ decay is given by,

$$\begin{equation}  \big\langle 0 | T  \exp \left[  i \int \,d^4x {\cal H} \right] | \pi ^- (  p _\pi )  \big\rangle  \end{equation}$$  
To lowest order this is given by,
$$\begin{equation}  i \int \,d^4x  \left\langle 0 | T W _\mu       J ^\mu  | \pi ^- (  p _\pi )  \right\rangle  \end{equation}$$  
If we square this quantity and integrate over phase space then we will get the decay rate.

On the other hand, the pion decay constant is defined through,

$$\begin{equation}  \left\langle 0 | J ^\mu | \pi ^- \right\rangle = - i f _\pi p _\pi ^\mu  \end{equation}$$  
This is clearly related to the above, but it seems to me there are a couple of subtleties. 

1. How do we get rid of the time-ordering symbol?
2. Since we don't have a value for $W _\mu$ how can we go ahead and extract $f _\pi$ ?

Comments

As far as I understand, we measure this constant experimentally, with help of calculations of the track properties.