You have to interchange the integration over paths and over time to obtain
G(x1,x0;t1,t0)=∫t1t0dt∫Dx exp[iℏ∫t1t0ds 12m˙x2](−iℏ V(x(t)))
The inner integral can be interpreted as a propagator again, except that the particle is now scattered at the potential V at the place x(t).
The inner path integral corresponds to the propagator of a free particle, and we can write
∫Dx exp[iℏ∫t1t0ds 12m˙x2]=G0(x1,x0;t1,t0)=∫dxdt′G0(x1,x;t1,t′)⋅G0(x,x0;t′,t0)δ(x−x(t))δ(t−t′)
This is the amplitude for a particle traveling from the point x0 to some point x and then to x1.
Another way of writing this is
⟨x1|U|x0⟩=∫dx⟨x1|U0|x⟩⟨x|U0|x0⟩(−iℏV(x))
Now, the Born scattering amplitude is just the Fourier transform of this. The free propagator U0 will give the terms involving energy, whereas the addition multiplication with V(x)corresponds to the additional matrix element.