In order to describe invariant forms on Dirac spinors $S$ one can find trivial subrepresentations in $S \otimes S$. If we use $S \cong (1/2, 0) \oplus (0, 1/2)$ then
\begin{multline}
[(1/2, 0) \oplus (0, 1/2)] \otimes [(1/2, 0) \oplus (0, 1/2)] =\\
(0, 0) \oplus (1, 0) \oplus (1/2, 1/2) \oplus (1/2, 1/2) \oplus (0, 1) \oplus (0, 0)
\end{multline}
Therefore representation theory predicts existence of two invariant forms. It is usually claimed that this two forms are
$$
D_1(\chi, \psi)=\bar{\chi}\psi=\chi^T\gamma_0\psi=\chi_R^T\psi_L+\chi_L^T\psi_R
$$
and
$$
D_2(\chi, \psi)=\bar{\chi}\gamma_5\psi=\chi^T\gamma_0 \gamma_5\psi=\chi_R^T\psi_L-\chi_L^T\psi_R
$$
The form $D_1$ is symmetric and it's quadratic form (with complex conjugation on the first argument) is usually used to construct Dirac's Lagrangian.
From the other hand, it is known that on Weyl spinors one can also find an antisymmetric invariant forms given as
$$
\chi^T_L\sigma_2\psi_L .
$$
Let me use this to construct one more anti-symmetric invariant form on Dirac spinors as a sum of two forms on Weyl spinors
$$
D_3(\chi, \psi)=\chi^T_L\sigma_2\psi_L+\chi^T_R\sigma_2\psi_R
$$
Form $D_3$ is not a linear combination of $D_1$ and $D_2$ and thus I get a contradiction with representation theory prediction. Where I made a mistake?
This post imported from StackExchange Physics at 2014-04-13 14:36 (UCT), posted by SE-user Sasha