Now the prominent Lee-Yang theorem (or Physical Review 87, 410, 1952) has almost become a standard ingredient of any comprehensive statistical mechanics textbook.
If the volume tends to infinity, some complex roots of the macro partition function may converge to some points z0,z1,z2,… on the real axis. Thus these {zn} divide the complex plane to some isolated phases. According to the singularity near the {zn} every two neighboring phases may have phase transition phenomena occurr.
Here comes my question. Considering three phases surrounding a triple point in a phase diagram, they can transit to each other (just think about water). Since neighborhood along the real axis consists of only two possibilities, I wonder if this theory could account for a description of the triple point. And what is the connection between neighborhood of patches on the complex plane and the neighborhood of phases in a phase diagram?
This post imported from StackExchange Physics at 2014-08-11 14:59 (UCT), posted by SE-user huotuichang