The answer is no.
The easiest way to see this I think it to look at the concrete embedding of SU(3)×SU(2)×U(1) in SU(5). That embedding is given by
(A,B,eiθ)↦(Aeiθ00Be−iθ)
.
Given this, one can simply just compute to see that the conjugate of something of this form is not necessarily of this form. For example, the conjugate of this by
−1√2(10i00i0100010i00i0100000√2)=:(XYUV)
is
(XAX∗eiθ+YBY∗e−iθXAU∗eiθ+YBV∗e−iθUAX∗eiθ+VBY∗e−iθUAU∗eiθ+VBV∗e−iθ)
.
Taking
θ:=0,A:=1√2(1i0i1000√2),B:=1√2(1ii1)
,
a computation shows that this conjugate is not in the sub-group of SU(5) listed above isomorphic to SU(3)×SU(2)×U(1).