(Qmechanic has already given the answer. However since i spent some time writing the answer below so i am anyway posting it)
Consider charged particle with charge q, and (nonzero) rest mass m moving in a spacetime with coordinates (x0,x1,...,xn−1). When there is no electromagnetic field then the action of particle is given as
S=−mc∫√ημν˙xμ(λ)˙xν(λ)dλ
Where λ is the parameter along the trajectory xμ(λ) of the particle and ˙xμ means ∂xμ(λ)/∂λ. Note that the action is Lorentz invariant. When there is a U(1) gauge field −iAμdxμ then we can add one more Lorentz invariant term to this action to generalize it as :-
S=−mc∫√ημν˙xμ(λ)˙xν(λ)dλ−(q/c)∫ημνAμ˙xμ(λ)dλ
Now in order to proceed its convenient to work in a particular inertial frame, and look at things from the viewpoint of inertial observer corresponding to that frame. In such a frame we can take x0(λ)/c=t=λ. Above integral was from some point λ0 to some λ1. Now it becomes an integral from t0=x0(λ0)/c to t1=x0(λ1)/c and can be written as
S=−mc2∫√1−v2/c2dt−∫(qA0−qc∑ivi.Ai)dt
So
L=−mc2√1−v2/c2−(qA0−qc∑ivi.Ai)
canonical momentum corresponding to xi can now be obtained as partial derivative of L wrt vi=dxi/dt and is given as :-
πi=mvi/√1−v2/c2+qcAi
Thus, as Qmechanic has answered, canonical momentum corresponding to i th coordinate is physical momentum along that coordinate plus a contribution from gauge potential.
Even without chosing a particular inertial frame we could find the canonical momentum πμ corresponding to xμ by taking the derivative of L in its covariant form wrt ˙xμ. This would give -
πμ=−mcημν˙xν/√ηαβ˙xα˙xβ−qcAμ
Now in classical mechanics above equation is nothing but a map from velocity space to phase space. Its only when we move to QM that we represent canonical momentums as derivatives wrt spatial coordinates. Again for convenience lets work in a particular inertial frame. Here momentum conjugate to xi is πi as given by the equation [5]. So as usual in QM we quantize by requiring the corresponding operators to satisfy
[Xi,Πj]=iδijℏ
We can represent this algebra on Hilbert space of functions on space Rn−1 (note that spacetime is Rn) by defining Xi to be the operator which acts as multiplication by xi, and Πi to be the operator which acts as the derivative −iℏ∂/∂xi. From equation [5] we see that
mechanicalmomentumoperator=−iℏ∂/∂xi−qcAi
Or taking −iℏ common we get
mechanicalmomentumoperator=−iℏ(∂/∂xi−iqcℏAi)=−iℏDi
Where Di=∂/∂xi−iqcℏAi
This post imported from StackExchange Physics at 2015-03-30 13:52 (UTC), posted by SE-user user10001