Consider a harmonic oscillator
H=12(p2+x2)
We make a canonical transformation to I=(p2+x2)/2 and φ=arctan(p/x). It is then easy to see that {I,φ}=1 and the Hamiltonian reduces to
H=I
We now canonically quantize this Hamiltonian and we obtain that ˆI=−iℏ∂φ. The stationary Schrödinger equation then simply reads
−iℏ∂φψ=Eψ
with the obvious solution ∼eiEnφ/ℏ,En=hn. However, this is different from the result En=h(n+1/2) we get by quantizing in the usual phase-space coordinates p,x.
This is a general pattern - it is very easy to find energy levels and other quantum numbers in action-angle coordinates but this will introduce a shift in the results as compared to the initial coordinate system.
This is probably a consequence of the nonlinear ∼pnxk nature of the transformation and will thus introduce O(ℏ) differences due to the operator ordering ambiguity of canonical quantisation.This makes me believe that these shifts will always be only shifts by a constant.
It is not clear to me
- Whether the observable consequences (such as En−Em=h(n−m)) are truly always independent of the phase-space coordinate system in which we execute canonical quantisation.
- How to compute the value of the shifts to the quantum numbers induced by the coordinate transform.
Does anyone know the answer to this?