Let's consider a single-particle(boson or fermion) with n states ϕ1,⋯,ϕn(normalized orthogonal basis of the single-particle Hilbert space), and let h be the single-particle Hamiltonian. As we all know, the second quantization Hamiltonian H=∑⟨ϕi∣hϕj⟩c†icj of h should not depend on the single-particle basis we choose(where ci,c†i are the bosonic or fermionic operators.), and this can be easily proved as follows:
Choose a new basis, say (˜ϕ1,⋯,˜ϕn)=(ϕ1,⋯,ϕn)U, where U is a n×n unitary matrix. Further, from the math viewpoint, an inner product can has two alternative definitions, say ⟨λ1ψ1∣λ2ψ2⟩=λ∗1λ2⟨ψ1∣ψ2⟩(1) or λ1λ∗2⟨ψ1∣ψ2⟩(2).
Now, if we think (˜c†1,⋯,˜c†n)=(c†1,⋯,c†n)U combined with the definition (1) for inner product, then it's easy to show that ∑⟨˜ϕi∣h˜ϕj⟩˜c†i˜cj=∑⟨ϕi∣hϕj⟩c†icj; On the other hand, if we think (˜c1,⋯,˜cn)=(c1,⋯,cn)U combined with the definition (2) for inner product, one can also show that ∑⟨˜ϕi∣h˜ϕj⟩˜c†i˜cj=∑⟨ϕi∣hϕj⟩c†icj.
Which combination of transformation for operators and definition for inner product is more reasonable? I myself prefer to the former one.
This post imported from StackExchange Physics at 2014-03-09 08:39 (UCT), posted by SE-user K-boy