It's not a "diagrammatic" proof, but you can see that this is in fact the "leading log" approximation from looking at what you get when you solve the Callan-Symanzik with the first loop Beta-function. Let's say I have some correlation function $\mathcal{G}(\lambda,\ell)$ which is a function of some marginal coupling $\lambda$ and $\ell \equiv \log \Lambda$ the log of the energy scale. Say the first loop $\beta$ function for $\lambda$ looks like
$\beta(\lambda) = b\lambda^2 + \mathcal{O}(\lambda^3)$
for some constant $b$. Just like scalar $\phi^4$ in $d=4$.
The CS equation looks like
$\left(\frac{\partial}{\partial\ell} - \beta(\lambda)\frac{\partial}{\partial\lambda}\right)\mathcal{G}(\lambda,\ell)$
Solving this equation with the lowest order $\beta$ function gives you $\mathcal{G}$ in the limit $\lambda \rightarrow 0$ but $\lambda\ell$ fixed. This is therefore the sum of the the terms leading in $\ell$ for every order of $\lambda$. You can see this by rewriting $\mathcal{G}$ in the following way:
$\mathcal{G}(\lambda,\ell) = \lambda\mathcal{G}^{(1)}(\lambda\ell) +\lambda^2\mathcal{G}^{(2)}(\lambda\ell) + \lambda^3\mathcal{G}^{(3)}(\lambda\ell) +\,\,...$
where the $\mathcal{G}^{(i)}$ are some unknown functions of a single variable. You can do this since there is a maximum level of divergence every order of perturbation theory. If you plug this in to the CS equation and keep track of the order of the terms you see you get a good differential equation for $\mathcal{G}^{(1)}$, but not for any of the higher order terms. If you went to the next order in $\lambda$ in the $\beta$ function that would give you a good equation for $\mathcal{G}^{(2)}$ which is the next to most divergent diagrams from every order of perturbation theory. So the RG procedure converts the limit $\lambda\rightarrow 0$, $\ell$ fixed that you get from standard perturbation theory, into the limit $\lambda\rightarrow 0$, $\lambda\cdot\ell$ fixed, which is frequently more useful.
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