For notational simplicity let's define
fl(q,σ):=(Ψ0,Ol(0)Ψq,σ)
Now the task is to show fl(q,σ) transforms in the same way as ul(q,σ) under homogeneous Lorentz transformation Λ, i.e. transforms as given in equation (5.1.19), which, together with irreducibility, defines ul(q,σ) uniquely up to a constant multiplication.
Due to the Lorentz invariance of vacuum and the fact Λ0=0, we have(adopting the repeated index summation convention)
fm(q,σ)=(Ψ0,U(Λ)Om(0)U−1(Λ)U(Λ)Ψq,σ)=D−1ml(Λ)(Ψ0,Ol(0)U(Λ)Ψq,σ),
which is equivalent to
Dlm(Λ)fm(q,σ)=(Ψ0,Ol(0)U(Λ)Ψq,σ).
Now substitute equation (2.5.11) to the RHS we get
Dlm(Λ)fm(q,σ)=√(Λp)0p0D(jn)σ′σ(W)(Ψ0,Ol(0)ΨqΛ,σ′)=√(Λp)0p0D(jn)σ′σ(W)fl(qΛ,σ′)
This is exactly (5.1.19).
Note that Dlm(Λ) is assumed to be irreducible in the book,
...where Ol(x) is a Heisenberg-picture operator, with the Lorentz transformation properties of some sort of free field ψl belonging to an irreducible representation of the homogeneous Lorentz group... (page 437)
hence by the discussion in chapter 5(e.g. content at the bottom of page 196), our function can differ ul(q,σ) only by a constant multiplication.