Rewrite the metric as follows:
ds2=V(dx+A)2+1V(dr2+r2dθ2+r2sin2θdϕ2)
This exhibits the Taub-NUT metric as the metric on the total space of a circle bundle over R2∖{0}. Let
ϑ1=√V(dx+A) ϑ2=1√Vdr
ϑ3=1√Vrdθ ϑ4=1√Vrsinθdϕ
so that we may write the metric as
ds2=ϑ21+ϑ22+ϑ23+ϑ24
and the volume form is
dvol=ϑ1∧ϑ2∧ϑ3∧ϑ4=r2sinθVdx∧dr∧dθ∧dϕ
If θ=π, then sinθ=0 and hence dvol=0, whence it is singular.